While it is rare, formed parts can develop fractures after they are placed in service. The vacuum breaker used on steamheated exchangers draws in ammonia from any leak in the ammonia refrigeration machine. Stress corrosion cracking of linepipe steels in anhydrous. Ammonia, buildingsplantequipment, health and safety. The main publications which have legally binding responsibilities for the owners of the systems are. At high pressure, corrosive ammonium carbamate may be formed. Corrosion failure modes in steam and condensate systems of ammonia plants. The results support a percolation model of dealloying and a filminduced cleavage model for stress corrosion cracking. Stress corrosion cracking of steel in liquefied ammonia service a.
Your tanks are the core of your brewery, so it is important to understand what scc is, what causes it, and what to do when your tanks suffer from this type of damage. American national standard for ansiiiar 22008, includes. Ammonia stress corrosion cracking is a form of stress corrosion cracking that commonly occurs in brass tubes in contaminated cooling water service. Permanent joints of pipes produced by hardsoldering of aluminiumaluminium and aluminiumaustenitic cr ni steels are mechanically solid and corrosion resistant.
Avoiding caustic stress corrosion cracking of refinery equipment and piping. This may result in ammonia weeping from a crack within the refrigeration system. The first heat exchangers with aluminium pipes were used in ammonia cycles. One of the most recognized forms of scc, chloride stress corrosion cracking appears as highly branched spiderweb cracks. Anhydrous ammonia stress corrosion cracking scc incident. Stress corrosion cracking scc is the growth of crack formation in a corrosive environment. Stress corrosion cracking in ammonia storage iffco. Carbon steel, alloy steel, and highstrength, quenched and tempered steel, when under applied or residual stress and especially when cold formed andor welded without subsequent thermal stress relief, are subject to failure by stress corrosion cracking scc in aircontaminated dry ammonia. It is generally understood that stress corrosion cracking can occasionally affect the high pressure vessels in ammonia refrigeration systems, but the nature of the. Stainless steels in ammonia production nickel institute. First, the part must be stressed, either from an applied force or due to residual stress usually from forming. Webcorr provides corrosion consultancy services, corrosion expert witness and corrosion short courses for inhouse training, online and distance learning. Guidelines for startup, inspection, and maintenance of ammonia mechanical refrigerating systems.
This recapitulation of experiences with stress corrosion cracking of steel in liquefied ammonia summarizes the subject over the last three decades. Stress corrosion cracking in refrigeration systems request pdf. Ammonia that is mixed with water is not corrosive to iron or steel. Refrigeration forums refrigeration divisions industrial nh3 stress corrosion cracking in nh3 vessels pda view full version. These parting limits corresponded identically to the onset of transgranular scc in both systems. Item detail stress corrosion cracking in the ammonia. Stress corrosion cracking of carbon steel storage tanks for. Astm b858062018, standard test method for ammonia vapor test for determining susceptibility to stress corrosion cracking in copper alloys, astm international, west conshohocken, pa, 2018, back to top. Development of engineering practice for ammonia plant equipment corrosion and material selection abstract our client, a north american company, requested fertilizer industrial services to develop a comprehensive guideline for engineering practice related to corrosion and selection of material specifically designed for ammonia plants. Zinc, copper and brass are some materials that should not be brought into contact with ammonia that contains water because ammonia corrosion can occur.
Very small concentrations 1 ppm or less can create a problem. The corrodent that causes stress corrosion cracking on copper or copper alloy tubes is ammonia. Its not uncommon in brass tubes in cooling water service that is contaminated with. The pressure system safety regulations 2000 pssr provision and use of work equipment regulations 1998 puwer. Introduction the following article is a followup to industry study indicates stress corrosion cracking in anhydrous ammonia storage vessels, which appeared in the october 1988 bulletin. Oxygen levels of more than a few ppm in liquid ammonia or a few thousand ppm in gaseous ammonia can promote stress corrosion cracking in steels. Guidelines for water contamination in ammonia refrigeration systems. Four factors, are required before stress corrosion cracking can occur. Equipment design and installation of ammonia mechanical refrigeration.
The stress can originate from an externally applied force, thermal stress, or residual stress. Transgranular stress corrosion cracking, tgscc, is observed in alloys with 20 or 30% zn but not in alloys with 0. Further progress is then a process alternating between corrosion and mechanical cracking. Stress corrosion cracking has been detected in ammonia storage tanks, spheres and other process equipment that is in contact with liquid ammonia. There are various uk and eu laws and regulations which apply to plants with ammonia refrigeration systems. The highest susceptibility to scc was found in liquid ammonia with 310 ppm oxygen and a water content lower than 100 ppm. Sections and equipment with most safety hazards in ammonia plants. The international institute of ammonia refrigeration makes no warranty or representation and assumes no. It is generally understood that stress corrosion cracking can occasionally affect the high pressure vessels in ammonia refrigeration systems, but the nature of the problem is often misrepresented. Stress corrosion cracking in a brewery paul mueller company. The stress corrosion cracking scc behavior of electricresistancewelded erw api grades x42, x46, x52, and x60 linepipe in liquid ammonia has been evaluated for the base metal, erw weldments, and girth weldments. The aluminium alloys intended for use in ammonia cycles are not affected by stress corrosion cracking. Condensed ammonia is a corrodent, and in anhydrous state it can cause stress corrosion cracking of stressed carbon steels or highstrength, lowalloy steels.
In that article, we identified a number of conditions that tend to promote or enable stress corrosion cracking. Water can be added to the ammonia to help prevent stress corrosion cracking. Our team was called in to verify damage to a coldstorage ammonia refrigeration system impacted by a fire. Problem, failure and safety analysis of ammonia plant.
Stress corrosion cracking issues in syngas plants that may. Ammonia or nitrides ammonia and nitrogen combinations, in the presence of moisture, cause this type of corrosion. It is clear that the major boilerhrsg failure mechanisms are driven by thermal andor cycle chemistry influences epri, 2003 effective cycle chemistry monitoring and control is required to. It can lead to unexpected sudden failure of normally ductile metal alloys subjected to a tensile stress, especially at elevated temperature. A modified design, incorporating annealing of the formed copper tube section, was recommended to avoid future failures. Electrochemistry of stress corrosion cracking of brass m. Electrochemistry of stress corrosion cracking of brass by. Stress corrosion cracking scc may get aggravated further due improper welding procedure.
The mechanism of stress corrosion cracking scc involves a very complicated sequence of corrosion and fracture. Stress corrosion cracking of carbon steel storage tanks. Ammonia stress corrosion cracking scc has been around a long time. The rate of dealloying increased almost discontinuously between 17 and 20 atom percent ao zn and between 11 and 16 ao al.
Covers ammonia characteristics and hazards, inspection and maintenance of equipment, startup issues, reference standards, safety equipment, and log book recordkeeping. Carbon steel in anhydrous ammonia can suffer from scc stress corrosion cracking. Ammonia scc is common in brass tubes with a cooling water function that have been polluted with ammonia due to biological growths or other impurities. The combined effect of water and oxygen on stress corrosion cracking of carbonmanganese steel in liquid and gaseous ammonia has been studied in detail. This condition generally requires a service temperature above 120 degrees 49c and general corrosion is very unlikely unless unusual contaminants are.
Stress corrosion cracking proceeds more rapidly at high temperatures. The information in the table below is our attempt at assembling a list of ammoniarefrigeration maintenance practices based on what we have read, seen, and heard. Stress corrosion cracking of cuzn and cua1 alloys in cuprous ammonia solutions can only occur when the parting limits for dealloying are exceeded. Stress corrosion cracking in refrigeration systems. Stress corrosion cracking ammonia psm rmp training. A modified design, incorporating annealing of the formed copper tube section, was recommended to. New informative appendix j stress corrosion cracking. Ammonia at high temperature has high potential for nitriding metals.
Equipment, design, and installation of closedcircuit. Stresscorrosion cracking in copper refrigerant tubing. This may result in a catastrophic failure of bulk storage vessels. Anhydrous ammonia in carbon steels and quenchedandtempered lowalloy steels in the presence of air in addition to stress, oxygen is a critical ingredient to enable scc nitrogen aggravates the process source. The combined effect of water and oxygen on stress corrosion cracking of. Electrochemistry of stress corrosion cracking of brass. Ammonia stress corrosion cracking can also affect carbon steel equipment, but unlike the. The relationship between dealloying and transgranular. Stress corrosion cracking scc can slowly destroy your brewery equipment without warning.
Stress corrosion cracking of steel in liquefied ammonia. This recapitulation of experiences with stresscorrosion cracking of steel in. Ammonia stress corrosion cracking nh3 scc in liquid ammonia storage tanks. Development of engineering practice for ammonia plant. This standard practice establishes guidelines to avoid caustic scc of equipment and piping. Scc was also found in three refrigeration system ammonia condensers. Stress corrosion cracking in the ammonia refrigeration industry 2007 stress corrosion cracking scc can occur on the inner surface of steel pressure vessels subjected to tensile stress, such as near major welds, in the presence of ammonia and oxygen. It has been shown that, for some materials, fine pitting is needed to start the activity. The cold front industrial refrigeration consortium. Stress corrosion cracking scc is difficult to predict and identify, and it can lead to catastrophic failure, often without any prior warning. How to make sure your ammonia refrigeration systems are safe. Scc is highly chemically specific in that certain alloys are likely to undergo scc only when exposed to a small number of chemical environments. Effects of water on the stress corrosion cracking of carbon steel in ethanolic media fortunate moyo a research report submitted to the faculty of engineering and the built environment, university of the witwatersrand, johannesburg, in partial fulfilment of the requirements for the degree of master of science in engineering johannesburg, 20. Corrosion in cold insulated systems insulation outlook.
Recall, two key ingredients are required to create stress corrosion cracking. This cracking can also occur when ammonia is intentionally added to process streams as a neutralizer by someone unaware of its potential effect on brass tubes. Carbon and lowalloy steels scc can occur in other materials stainless steel. May be outofdate not yet updated following may 2019 publication of iiar standard 6, inspection, testing, and maintenance of closedcircuit ammonia refrigeration systems. Although equipment damage was obvious in the immediate area of the fire, there was concern over whether the system sustained internal damage. Ammonia stress corrosion cracking is a form of stress corrosion cracking that commonly occurs in brass tubes in cooling water service that has been contaminated with ammonia due to biological growths or other contamination. On discovery of a source of moist ammonia in the system, associated with the location of failure, intergranular stress corrosion cracking scc was identified as the failure mechanism. However, stress corrosion cracking continues to be a problem in aging plants and must be considered when completing risk based inspection rbi. Elements scc capabilities help to quickly evaluate the susceptibility of metallic materials to cracking and determine the size and scope of the problem before the failure occurs, avoiding major. The committee determined that the failures were most likely caused by stress corrosion cracking and that the probability of cracking increased as the yield strength of the steel increased. It is generally understood that stress corrosion cracking can occasionally affect the high pressure vessels in ammonia refrigeration systems, but the nature of the problem is often misrepresented in design codes, safety standards and textbooks and ways in which the initiation of stress corrosion can be prevented are ignored. Austenitic stainless steel pipe and equipment is unlikely to develop stress corrosion cracking scc, provided the metals temperature is kept cool. Stress corrosion crack growth of carbon steel in ammonia was studied with. To combat this, we recommend insulation materials such as armaflex, which has a mass share of ammonia that.